Synthesis of Poly(5-norbornene-2,3-dicarboxylic Anhydride) by ROMP in the Presence of the Second-Generation Grubbs Catalyst and 1-Hexene in DMF
The results of investigations on the ring-opening metathesis polymerization (ROMP) of 5-norbornene-2,3-dicarboxylic acid anhydride (NDA) under the action of the second-generation Grubbs catalyst in the presence of 1-hexene, acting as a chain transfer agent, in DMF in order to synthesize a soluble low-molecular-weight polymer containing reactive groups are presented. The effect of polymerization conditions on the molecular weight and thermal properties of the resulting metathesis polymers based on NDA was determined.
Authors
- Igor S. Ignatyev (ORCID: https://orcid.org/0000-0002-4476-274X)
- N. P. Bezrukov (ORCID: https://orcid.org/0000-0001-9869-3834)
- С. В. Антонов (ORCID: https://orcid.org/0000-0002-8966-7906)
- A. A. Morontsev (ORCID: https://orcid.org/0000-0002-8526-9302)
- Maxim V. Bermeshev (ORCID: https://orcid.org/0000-0003-3333-4384)
- Viktoria Y. Melekhina
Publication Details
- Journal
- INEOS OPEN
- Published
- 2025-04-29
- DOI
- https://doi.org/10.32931/io2514a
- Primary Topic
- Synthetic Organic Chemistry Methods
- Type
- article
- Field-Weighted Citation Impact
- 0.00