Synthesis and Structure of [Sb(m2-O)Cl(DMSO-О)]n
New complex [Sb(m2-O)Cl(DMSO-О)]n was obtained by the interaction of tris(2,6-dimethoxyphenyl)stibine with HCl in chloroform followed by the recrystallization of the product from DMSO. X-ray diffraction analysis revealed a distorted trigonal bipyramidal bisphenoidal environment of the antimony atoms, with the axial angles O–Sb–Cl of 163.8(3), 164.1(3)° and the interatomic distances m2-O–Sb and Sb–Oax of 1.948(9), 1.973(9) Å and 2.242(10), 2.194(11) Å, respectively.
Authors
- И.В. Егорова (ORCID: https://orcid.org/0000-0001-8799-608X)
- Н. В. Первухина (ORCID: https://orcid.org/0000-0001-6200-5657)
- Н. А. Родионова (ORCID: https://orcid.org/0000-0002-8682-2675)
- В. В. Жидков (ORCID: https://orcid.org/0000-0001-5315-1759)
- Natalia V. Kuratieva (ORCID: https://orcid.org/0000-0001-5993-2900)
- I. N. Nesina
Publication Details
- Journal
- INEOS OPEN
- Published
- 2025-04-29
- DOI
- https://doi.org/10.32931/io2515a
- Primary Topic
- Organometallic Compounds Synthesis and Characterization
- Type
- article
- Field-Weighted Citation Impact
- 0.00