One-pot synthesis of atomically precise chiral PtAg<sub>4</sub> nanoclusters
We report the synthesis and structural characterization of [PtAg<sub>4</sub>Cl(BDPP)<sub>4</sub>H]<sup>2+</sup>, a novel bimetallic complex featuring an intrinsically chiral architecture. The heterometallic Pt-Ag core exhibits distinctive optical properties, while the chiral BDPP (BDPP is 2,4-bis(diphenylphosphino)pentane) ligand not only induces structural asymmetry but also fine-tunes the electronic and steric characteristics of the complex.
Authors
- Jinrun Dong (ORCID: https://orcid.org/0000-0002-4438-7310)
- Jian Hou (ORCID: https://orcid.org/0000-0001-8759-8081)
- Yanru Yin (ORCID: https://orcid.org/0000-0002-3937-0389)
- Hongli Jia
- Huifang Guo
- Yujie Zhang (ORCID: https://orcid.org/0000-0002-0790-418X)
- Simin Li (ORCID: https://orcid.org/0000-0001-7497-3225)
- Hui Cun Shen (ORCID: https://orcid.org/0000-0003-4800-437X)
- Xin Chen (ORCID: https://orcid.org/0000-0001-8305-6592)
- Qi Li (ORCID: https://orcid.org/0009-0006-4729-0289)
Institutions
- Peking University (CN)
- Inner Mongolia University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03572d
- Citations
- 2
- Primary Topic
- Nanocluster Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.04
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Inner Mongolia
- National Key Research and Development Program of China