ZnO/PVDF Nanogenerators with Hemisphere-Patterned PDMS for Enhanced Piezoelectric Performance

In this study, we present a flexible piezoelectric nanogenerator based on a zinc oxide (ZnO)/polyvinylidene fluoride (PVDF) nanocomposite electrospun onto a hemisphere-patterned PDMS substrate. The nanogenerator was fabricated by replicating a silicon mold with inverted hemispheres into PDMS, followed by direct electrospinning of ZnO-dispersed PVDF nanofibers. Varying the ZnO concentration from 0.6 to 1.4 wt% allowed us to evaluate its effect on structural, dielectric, and piezoelectric properties. The nanogenerator containing 0.8 wt% ZnO exhibited the thinnest fibers (371 nm), the highest β-phase fraction (85.6%), and the highest dielectric constant (35.8). As a result, it achieved the maximum output voltage of 7.30 V, with excellent signal consistency under an applied pressure of 5 N. Comparisons with pristine PVDF- and ZnO/PVDF-only devices demonstrated the synergistic effect of ZnO loading and patterned PDMS on the enhancement of piezoelectric output. The hemisphere-patterned PDMS substrate improved the mechanical strain distribution, interfacial contact, and charge collection efficiency. These results highlight the potential of ZnO/PVDF/PDMS hybrid nanogenerators for use in wearable electronics and self-powered sensor systems.