Isomerism and transformation of Zr-hydroxamate metal–organic frameworks
Phase transformation was investigated for stable Zr-hydroxamate and Zr-carboxylate MOFs. First, the benchmark UiO-66 could easily convert into three isomeric Zr-hydroxamate MOFs, all boasting exceptional chemical robustness. Further, within the Zr-hydroxamate family, it was also discovered that "metastable" phases could readily isomerize into a thermodynamic product.
Authors
- Yuqing Qiu (ORCID: https://orcid.org/0000-0002-0745-3155)
- Chong Liu (ORCID: https://orcid.org/0000-0002-9780-9062)
- Zhen‐Wu Shao
- Chaozhi Xiong
Institutions
- Sichuan University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03911h
- Citations
- 1
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.54
Funders
- National Natural Science Foundation of China