Mitigating clay swelling and permeability loss in thermal EOR with a quaternary ammonium clay stabilizer under high-temperature low-salinity conditions

Clay swelling and fines migration pose significant challenges to thermally enhanced oil recovery (EOR) operations, particularly in clay-rich formations. This study systematically investigates clay swelling behavior and permeability impairment under high-temperature, low-salinity (HTLS) conditions and evaluates various inhibition methods to mitigate formation damage. To ensure realistic analysis, data and materials from a field with similar issues in Kazakhstan were used. Static/dynamic swelling tests demonstrated that a quaternary ammonium-based inhibitor consistently provided superior clay stabilization through effective ion exchange and surface charge modification mechanisms. In distilled water at 100 °C, inhibitor-treated samples maintained 48.89 % of their original permeability, while untreated samples exhibited severe damage, retaining only 17.05 %. Additionally, this chemical inhibitor significantly lowered the critical salt concentration (CSC), effectively stabilizing clay at 4920 ppm salinity compared to 7380 ppm required without treatment. Scanning electron microscopy (SEM) imaging corroborated these results, revealing that inhibitor-treated clay maintains a compact and coherent structure, in stark contrast to the pronounced swelling, delamination, and structural deterioration observed in untreated clay samples. Nevertheless, this quaternary ammonium-based clay stabilizer presents a robust and promising solution for reducing clay swelling-induced damage, sustaining reservoir permeability, and improving thermal EOR performance in swelling-prone formations. • A quaternary ammonium-based inhibitor effectively mitigates clay swelling and permeability loss in HTLS conditions. • Inhibitor-treated samples retain 48.89 % permeability at 100 °C, while untreated samples only 17.05 %. • The inhibitor lowers the CSC from 7380 ppm to 4920 ppm, enhancing clay stability. • SEM imaging confirms reduced swelling and preserved clay structure in treated samples, improving thermal EOR efficiency.

Authors

Institutions

Publication Details

Journal
Energy Geoscience
Published
2025-07-26
DOI
https://doi.org/10.1016/j.engeos.2025.100444
Citations
3
Primary Topic
Seismic Imaging and Inversion Techniques
Type
article
Field-Weighted Citation Impact
5.60
Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Mitigating clay swelling and permeability loss in thermal EOR with a quaternary ammonium clay stabilizer under high-temperature low-salinity conditions

Peyman Pourafshary, Aisha Labak
3 citations
Energy Geoscience
Seismic Imaging and Inversion Techniques
5.60
article

Mitigating clay swelling and permeability loss in thermal EOR with a quaternary ammonium clay stabilizer under high-temperature low-salinity conditions

Peyman Pourafshary, Aisha Labak
article en
3 citations

Abstract

Clay swelling and fines migration pose significant challenges to thermally enhanced oil recovery (EOR) operations, particularly in clay-rich formations. This study systematically investigates clay swelling behavior and permeability impairment under high-temperature, low-salinity (HTLS) conditions and evaluates various inhibition methods to mitigate formation damage. To ensure realistic analysis, data and materials from a field with similar issues in Kazakhstan were used. Static/dynamic swelling tests demonstrated that a quaternary ammonium-based inhibitor consistently provided superior clay stabilization through effective ion exchange and surface charge modification mechanisms. In distilled water at 100 °C, inhibitor-treated samples maintained 48.89 % of their original permeability, while untreated samples exhibited severe damage, retaining only 17.05 %. Additionally, this chemical inhibitor significantly lowered the critical salt concentration (CSC), effectively stabilizing clay at 4920 ppm salinity compared to 7380 ppm required without treatment. Scanning electron microscopy (SEM) imaging corroborated these results, revealing that inhibitor-treated clay maintains a compact and coherent structure, in stark contrast to the pronounced swelling, delamination, and structural deterioration observed in untreated clay samples. Nevertheless, this quaternary ammonium-based clay stabilizer presents a robust and promising solution for reducing clay swelling-induced damage, sustaining reservoir permeability, and improving thermal EOR performance in swelling-prone formations. • A quaternary ammonium-based inhibitor effectively mitigates clay swelling and permeability loss in HTLS conditions. • Inhibitor-treated samples retain 48.89 % permeability at 100 °C, while untreated samples only 17.05 %. • The inhibitor lowers the CSC from 7380 ppm to 4920 ppm, enhancing clay stability. • SEM imaging confirms reduced swelling and preserved clay structure in treated samples, improving thermal EOR efficiency.

Energy GeoscienceVol. 6(4)
Nazarbayev University (KZ)
Climate action
Openalex Percentile: Top 4%
Seismic Imaging and Inversion Techniques
5.60
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.