Theoretical investigations of the catalytic antioxidation mechanism of diarylamine and the coordination effects of Fe(<scp>iii</scp>) and Fe atoms
A new catalytic antioxidation mechanism of diarylamines is proposed, highlighting a β -H transfer pathway via ROO˙ radicals, which shows that Fe( iii ) coordination significantly enhances radical-scavenging efficiency.
Authors
- Weiguo Xue
- Xiaowei Xu (ORCID: https://orcid.org/0000-0002-8629-4438)
- Yi Luo (ORCID: https://orcid.org/0000-0002-6256-4595)
- Dejun Shi
- Junming Wang (ORCID: https://orcid.org/0000-0002-7447-8803)
- Kebin Chi
- Huiying Lv
- Hao Li (ORCID: https://orcid.org/0000-0002-7577-1366)
- Yufeng Liu (ORCID: https://orcid.org/0000-0002-2733-7733)
- Tong Li (ORCID: https://orcid.org/0000-0001-5729-1839)
- C.-C. Wei
- Zhuozheng Wang (ORCID: https://orcid.org/0009-0000-8020-8001)
- Q. Kong
Institutions
- Beijing Institute of Petrochemical Technology (CN)
- Dalian University of Technology (CN)
- Dalian University (CN)
- Lanzhou Petrochemical Polytechnic (CN)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj02543e
- Citations
- 1
- Primary Topic
- Free Radicals and Antioxidants
- Type
- article
- Field-Weighted Citation Impact
- 0.94