Silicon(<scp>iv</scp>) tetraazachlorin – an unusual cycloaddition product from 3,4-diphenyl-1<i>H</i>-pyrrole-2,5-diimine
Template cyclotetramerization of crude 3,4-diphenyl-1<i>H</i>-pyrrole-2,5-diimine with SiCl<sub>4</sub> leads to, along with the expected Si(IV) octaphenylporphyrazine, an unusual side-product - a silicon(IV) tetraazachlorin containing a fused pyrrolo[1,2-<i>a</i>]imidazolone moiety.
Authors
- Ekaterina D. Rychikhina (ORCID: https://orcid.org/0000-0001-8728-2538)
- Dmitriy A. Lazovskiy (ORCID: https://orcid.org/0000-0001-7046-516X)
- Pavel A. Stuzhin (ORCID: https://orcid.org/0000-0002-1347-3654)
- Н. В. Сомов (ORCID: https://orcid.org/0000-0001-9460-307X)
- Svetlana S. Ivanova (ORCID: https://orcid.org/0000-0001-8379-3322)
Institutions
- Ivanovo State University (RU)
- Ivanovo State University of Chemistry and Technology (RU)
- N. I. Lobachevsky State University of Nizhny Novgorod (RU)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt01113b
- Primary Topic
- Porphyrin and Phthalocyanine Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Foundation for Basic Research