Exploration of e<sub>g</sub> orbital occupancy in Prussian blue analogues for enhanced oxygen evolution reaction
A correlation between the e<sub>g</sub> orbital occupancy of metal active sites and the oxygen evolution reaction (OER) performance has been investigated for four Prussian blue analogues, specifically FeCNM<sub>A</sub> PBAs, where M<sub>A</sub> represents Fe, Co, Ni, and Cu. Among them, FeCNCo PBA demonstrates superior electrocatalytic OER performance, validating the impact of manipulating the electronic configuration of the M<sub>A</sub> site on the OER performance.
Authors
- Nan Jiang (ORCID: https://orcid.org/0000-0002-1130-4478)
- Li Guicheng
Institutions
- Guizhou University (CN)
- Guizhou Minzu University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02444g
- Citations
- 1
- Primary Topic
- Electrocatalysts for Energy Conversion
- Type
- article
- Field-Weighted Citation Impact
- 0.36