Excitation of Molecules and Atoms for Astrophysics (EMAA): A spectroscopic and collisional database

Context . In astrophysical environments, the energy levels of molecules, atoms, and ions are rarely populated at local thermodynamic equilibrium (LTE), that is the level populations reflect the competition between radiative and collisional processes. Interpreting non-LTE spectra therefore requires knowing both the Einstein radiative coefficients and the collisional rate coefficients. For a long time, inelastic collision calculations were limited to the most abundant and simple species, but they have now entered a new era thanks to the increase of computer power and the development of high-accuracy potential energy surfaces. Aims . With the advent of observatories with powerful spectral capabilities, such as ALMA or the JWST, and the wealth of new species detected, obtaining collisional rate coefficients quickly has become essential. We aim to provide the community with atomic and molecular data available from the literature for an ever-increasing number of systems. Methods . We have developed a database hosting both the collisional and spectroscopic data necessary to interpret spectra of non-LTE environments such as the (extra)galactic interstellar media, star-forming regions, and cometary atmospheres. We provide data files that can be employed directly in widely used non-LTE radiative transfer codes such as RADEX . Results . To date, the database contains 106 targets, including nuclear-spin isomers and isotopologues and nine possible projectiles (ortho-H 2 , para-H 2 , H, H + , electrons, He, CO, ortho-H 2 O and para-H 2 O, depending on the targets), for a total of 311 target-projectile data files.

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Publication Details

Journal
Astronomy and Astrophysics
Published
2025-07-24
DOI
https://doi.org/10.1051/0004-6361/202554403
Citations
10
Primary Topic
Laser-induced spectroscopy and plasma
Type
article
Field-Weighted Citation Impact
8.64

Funders

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article

Excitation of Molecules and Atoms for Astrophysics (EMAA): A spectroscopic and collisional database

A. Bacmann, Alexandre Faure, Raymond G. Jacquot
10 citations
Astronomy and Astrophysics
Laser-induced spectroscopy and plasma
8.64
article

Excitation of Molecules and Atoms for Astrophysics (EMAA): A spectroscopic and collisional database

A. Bacmann, Alexandre Faure, Raymond G. Jacquot
article en
10 citations

Abstract

Context . In astrophysical environments, the energy levels of molecules, atoms, and ions are rarely populated at local thermodynamic equilibrium (LTE), that is the level populations reflect the competition between radiative and collisional processes. Interpreting non-LTE spectra therefore requires knowing both the Einstein radiative coefficients and the collisional rate coefficients. For a long time, inelastic collision calculations were limited to the most abundant and simple species, but they have now entered a new era thanks to the increase of computer power and the development of high-accuracy potential energy surfaces. Aims . With the advent of observatories with powerful spectral capabilities, such as ALMA or the JWST, and the wealth of new species detected, obtaining collisional rate coefficients quickly has become essential. We aim to provide the community with atomic and molecular data available from the literature for an ever-increasing number of systems. Methods . We have developed a database hosting both the collisional and spectroscopic data necessary to interpret spectra of non-LTE environments such as the (extra)galactic interstellar media, star-forming regions, and cometary atmospheres. We provide data files that can be employed directly in widely used non-LTE radiative transfer codes such as RADEX . Results . To date, the database contains 106 targets, including nuclear-spin isomers and isotopologues and nine possible projectiles (ortho-H 2 , para-H 2 , H, H + , electrons, He, CO, ortho-H 2 O and para-H 2 O, depending on the targets), for a total of 311 target-projectile data files.

Astronomy and AstrophysicsVol. 700
Centre National de la Recherche Scientifique (FR), Université Grenoble Alpes (FR)
Centre National d’Etudes Spatiales, Centre National de la Recherche Scientifique
Openalex Percentile: Top 2%
Laser-induced spectroscopy and plasma
8.64
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