Tailoring the properties of Sb <sup>3+</sup> -doped in-based organic–inorganic hybrid metal halides through A-site cation engineering
This study explores how A-site cation engineering and Sb<sup>3+</sup> doping alter the structure and optical properties of two zero-dimensional (0D) organic-inorganic hybrid metal halides (OIHMHs). Incorporating C<sub>4</sub>H<sub>10</sub>SN<sup>+</sup> (TMPL = protonated thiomorpholine) into (Ph<sub>3</sub>S)<sub>2</sub>InCl<sub>5</sub>:Sb<sup>3+</sup> (Ph<sub>3</sub>S = triphenylsulfonium cation) forms (Ph<sub>3</sub>S)(TMPL)<sub>2</sub>InCl<sub>6</sub>:Sb<sup>3+</sup>, causing a blue-shift in emission from orange-red to yellow.
Authors
- Yuexiao Pan (ORCID: https://orcid.org/0000-0003-4805-4983)
- Yingnuo Chen
- Hong‐Ping Xiao (ORCID: https://orcid.org/0000-0001-7242-7976)
- Jun Zou (ORCID: https://orcid.org/0000-0003-4720-2040)
- Yali Tang
- Ying� Qin (ORCID: https://orcid.org/0000-0003-4365-586X)
Institutions
- Wenzhou University (CN)
- Institute of New Materials (CN)
- Shanghai Institute of Technology (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03205a
- Citations
- 1
- Primary Topic
- Solid-state spectroscopy and crystallography
- Type
- article
- Field-Weighted Citation Impact
- 0.52