Effects of Synthesis Conditions on the Physicochemical Properties and Hemolytic Activity of Beta Zeolites

The study investigates the effects of synthesis conditions on the physicochemical properties and biological activity of Beta zeolites. Specifically, it addresses the effects of the tetraethylammonium hydroxide (TEAOH) content in the reaction mixture on the crystallinity, particle size and morphology, textural properties, acidity, and hemolytic activity of the zeolites synthesized. Reducing the TEAOH content by factors of 2, 4, and 6 compared to the reference composition was found to lower the zeolite crystallinity, increase the mean particle size (from 240 to 515 nm), change the particle morphology, and reduce the concentration of acid sites (from 822 to 638 µmol/g). Hemolytic activity tests demonstrated that the zeolite toxicity for human erythrocytes increased with a reduction in the TEAOH content.

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Journal
Petroleum Chemistry
Published
2025-04-01
DOI
https://doi.org/10.1134/s0965544125600973
Primary Topic
Zeolite Catalysis and Synthesis
Type
article
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article

Effects of Synthesis Conditions on the Physicochemical Properties and Hemolytic Activity of Beta Zeolites

E. Yu. Brazovskaya, O. Yu. Golubeva, О. В. Шамова, Yu. A. Alikina et al.
Petroleum Chemistry
Zeolite Catalysis and Synthesis
article

Effects of Synthesis Conditions on the Physicochemical Properties and Hemolytic Activity of Beta Zeolites

E. Yu. Brazovskaya, O. Yu. Golubeva, О. В. Шамова, Yu. A. Alikina, A. Yu. Artamonov
article en

Abstract

The study investigates the effects of synthesis conditions on the physicochemical properties and biological activity of Beta zeolites. Specifically, it addresses the effects of the tetraethylammonium hydroxide (TEAOH) content in the reaction mixture on the crystallinity, particle size and morphology, textural properties, acidity, and hemolytic activity of the zeolites synthesized. Reducing the TEAOH content by factors of 2, 4, and 6 compared to the reference composition was found to lower the zeolite crystallinity, increase the mean particle size (from 240 to 515 nm), change the particle morphology, and reduce the concentration of acid sites (from 822 to 638 µmol/g). Hemolytic activity tests demonstrated that the zeolite toxicity for human erythrocytes increased with a reduction in the TEAOH content.

Petroleum ChemistryVol. 65(4)
Institute of Experimental Medicine (RU), Institute of Chemistry of Silicates named after I.V. Grebenshchikov (RU)
Zero hunger
Openalex Percentile: Top 85%
Zeolite Catalysis and Synthesis
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