Rh<sub>2</sub>(<scp>ii</scp>)-catalyzed cyclization/<i>gem</i>-hydrosilylation of benzene-fused 1,6-enynones
Dirhodium( ii )-catalyzed cyclization/geminal hydrosilylation of 1,6-enynes that accommodates primary, secondary and tertiary silanes is reported. This protocol enables one-step synthesis of bicyclo[3.1.0]hexanone silanes and naphthol-derived silanes.
Authors
- Shifa Zhu (ORCID: https://orcid.org/0000-0001-5172-7152)
- Zurong Xu
- Jiajun Lu
- Rui Wu (ORCID: https://orcid.org/0000-0001-8311-6014)
Institutions
- Zhejiang Sci-Tech University (CN)
- Nankai University (CN)
- South China University of Technology (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00835b
- Primary Topic
- Catalytic Alkyne Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Basic and Applied Basic Research Foundation of Guangdong Province