Mathematical Model of the Functional Interrelation between Electrode Potential and Electrode Affinity

The question concerns the determination of the ratio and interrelation between two important quantities (electrode potential, reduction potential (Reduction potentials), and electron affinity) in most elements of the periodic table of Mendeleev; I have derived a general formula describing this interrelation:where the formula takes into account both the number of external valence electrons ( e n ) And the ordinal number in the periodic table of Mendeleyev.With this arrangement, the internal periodicity of the electrode potentials is revealed by the ordinal number.It is clear from the table that the theoretical results are in good agreement with the experiment.The experimental results are given in the table.I also showed in the corresponding formula that the rate constant of a chemical reaction and the constant of chemical equilibrium depend on such an important quantity as the electron affinity.I have provided relevant literature sources and studies describing the interrelation between the above-mentioned quantities (reduction potential and electron affinity) in such widely studied substances as fullerenes, aromatic hydrocarbons and metal complexes.