Hydrothermal synthesis of nanohydroxyapatite-activated carbon composites and its slow-release performance for urea

Urea is the most widely used nitrogen-based fertilizer, but its excessive application leads to nutrient loss through leaching and evaporation. This study presents a nanohydroxyapatite (nHA)-activated carbon (AC) composite synthesized via hydrothermal method as a slow-release material (SRM) for urea. The composites of nHA-AC (HC) enhances urea adsorption and release control. Structural and functional group of composites were confirmed by XRD and FTIR, while TEM revealed nHA nanorods coating the surface of AC. Furthermore, zeta potential and surface area of HC showed a better properties than pure nHA. The composite HC1 (nHA:AC = 75:25) showed the best performance, releasing only 17% of urea over 240 min and adsorbing 0.54 g<sub>urea</sub>/g<sub>SRM</sub> (36.2%). These results highlight the potential of HC1 as an efficient slow-release fertilizer to improve nutrient use efficiency in agriculture.

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Journal
Scientific Reports
Published
2025-07-19
DOI
https://doi.org/10.1038/s41598-025-09023-w
Primary Topic
Polymer-Based Agricultural Enhancements
Type
article
Field-Weighted Citation Impact
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article

Hydrothermal synthesis of nanohydroxyapatite-activated carbon composites and its slow-release performance for urea

Guoqing Guan, Azman Ma’amor, Diana Rakhmawaty Eddy, Atiek Rostika Noviyanti et al.
Scientific Reports
Polymer-Based Agricultural Enhancements
article

Hydrothermal synthesis of nanohydroxyapatite-activated carbon composites and its slow-release performance for urea

Guoqing Guan, Azman Ma’amor, Diana Rakhmawaty Eddy, Atiek Rostika Noviyanti, Bedah Rupaedah, Irwan Kurnia, Suryana, Sabila Aulia Hemzah
article en

Abstract

Urea is the most widely used nitrogen-based fertilizer, but its excessive application leads to nutrient loss through leaching and evaporation. This study presents a nanohydroxyapatite (nHA)-activated carbon (AC) composite synthesized via hydrothermal method as a slow-release material (SRM) for urea. The composites of nHA-AC (HC) enhances urea adsorption and release control. Structural and functional group of composites were confirmed by XRD and FTIR, while TEM revealed nHA nanorods coating the surface of AC. Furthermore, zeta potential and surface area of HC showed a better properties than pure nHA. The composite HC1 (nHA:AC = 75:25) showed the best performance, releasing only 17% of urea over 240 min and adsorbing 0.54 g<sub>urea</sub>/g<sub>SRM</sub> (36.2%). These results highlight the potential of HC1 as an efficient slow-release fertilizer to improve nutrient use efficiency in agriculture.

Scientific ReportsVol. 15(1)
Hirosaki University (JP), University of Malaya (MY), Indonesian Agency for Agricultural Research and Development (ID), National Research and Innovation Agency (ID), Padjadjaran University (ID)
Badan Riset dan Inovasi Nasional, Lembaga Pengelola Dana Pendidikan
Zero hunger
Openalex Percentile: Top 84%
Polymer-Based Agricultural Enhancements
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Hydrothermal synthesis of nanohydroxyapatite-activated carbon composites and its slow-release performance for urea — Guoqing Guan, Azman Ma’amor, et al. · Scientific Reports (2025) | TGRS Research Map | TGRS