Photoredox-catalyzed arylation of isonitriles by diaryliodonium salts towards benzamides
The arylation of isonitriles by diaryliodonium salts under photoredox conditions has been proposed for the first time. The suggested procedure allows preparing a broad range of benzamides using both symmetric and unsymmetric diaryliodonium salts under mild conditions. A plausible mechanism for the reaction and the selectivity of aryl transfer (in case of unsymmetrical iodonium salts) were studied.
Authors
- Natalia S. Soldatova (ORCID: https://orcid.org/0000-0002-1738-4747)
- Mikhail A. Kinzhalov (ORCID: https://orcid.org/0000-0001-5055-1212)
- Nikita S. Antonkin
- Nadezhda M Metalnikova (ORCID: https://orcid.org/0000-0002-4498-0982)
- Tuan K. Nguyen (ORCID: https://orcid.org/0000-0002-7881-7630)
- Павел Сергеевич Постников (ORCID: https://orcid.org/0000-0001-9713-1290)
- Alexander V. Nyuchev (ORCID: https://orcid.org/0000-0002-0460-0543)
Institutions
- St Petersburg University (RU)
- National Research Tomsk State University (RU)
- Tomsk Polytechnic University (RU)
- N. I. Lobachevsky State University of Nizhny Novgorod (RU)
Publication Details
- Journal
- Beilstein Journal of Organic Chemistry
- Published
- 2025-07-21
- DOI
- https://doi.org/10.3762/bjoc.21.110
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Science Foundation
- Division of Materials Research