Development of highly efficient resin-based Ag–π nanocatalysts <i>via</i> an <i>in situ</i> catalytic strategy for selective cinnamaldehyde hydrogenation

This study presents ion-exchange resin-based Ag-π nanocatalysts synthesized <i>via</i> an <i>in situ</i> catalytic strategy. Ag/RS-180 demonstrates 100% conversion and selectivity for cinnamaldehyde hydrogenation, while Ag/RS, lacking π-carbon, exhibits only 5-12% conversion. The local conjugated network functions as an efficient electron pool, donating electrons to facilitate the reduction of cinnamaldehyde.

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Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc03284a
Primary Topic
Nanomaterials for catalytic reactions
Type
article
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article

Development of highly efficient resin-based Ag–π nanocatalysts via an in situ catalytic strategy for selective cinnamaldehyde hydrogenation

Huaiyu Zhang, Desong Wang, Zhengquan Li, Qingyang Zhou et al.
Chemical Communications
Nanomaterials for catalytic reactions
article

Development of highly efficient resin-based Ag–π nanocatalysts via an in situ catalytic strategy for selective cinnamaldehyde hydrogenation

Huaiyu Zhang, Desong Wang, Zhengquan Li, Qingyang Zhou, Duoqiang Wang, Yandong Duan, Suqin Zhang, Qingzhi Luo
article en

Abstract

This study presents ion-exchange resin-based Ag-π nanocatalysts synthesized <i>via</i> an <i>in situ</i> catalytic strategy. Ag/RS-180 demonstrates 100% conversion and selectivity for cinnamaldehyde hydrogenation, while Ag/RS, lacking π-carbon, exhibits only 5-12% conversion. The local conjugated network functions as an efficient electron pool, donating electrons to facilitate the reduction of cinnamaldehyde.

Chemical CommunicationsVol. 61(68)
Hebei University of Technology (CN), Hebei University of Science and Technology (CN), Yanshan University (CN), Hebei Normal University (CN)
Openalex Percentile: Top 87%
Nanomaterials for catalytic reactions
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