Unlocking high selectivity and stability of a cobalt-based catalyst in the <i>n</i>-butanol amination reaction
Acid treatment selectively removes large Co 3 O 4 nanoparticles. Well-dispersed Co species suppress C–N over-coupling and carbon deposition, achieving 87.8% n -butylamine selectivity with 120 h stability at WHSV = 2.5 h −1 .
Authors
- Wen Liu (ORCID: https://orcid.org/0000-0002-6787-2431)
- Xinbao Zhang (ORCID: https://orcid.org/0000-0002-6588-2310)
- Xiujie Li (ORCID: https://orcid.org/0000-0002-2649-4673)
- Xiangxue Zhu (ORCID: https://orcid.org/0000-0002-0658-9173)
- Shaoguo Li
- Fuwei Gan (ORCID: https://orcid.org/0000-0001-5757-9293)
- Min Qian (ORCID: https://orcid.org/0000-0003-1214-8830)
- Junjie Li (ORCID: https://orcid.org/0009-0006-7766-7745)
- Yu‐Zhong Wang (ORCID: https://orcid.org/0000-0001-8694-4106)
Institutions
- Dalian Institute of Chemical Physics (CN)
- Chinese Academy of Sciences (CN)
- University of Chinese Academy of Sciences (CN)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cy00700c
- Citations
- 1
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.54