Zn–N3 complexes for the cycloaddition of epoxides with CO <sub>2</sub> at atmospheric pressure
Eight Zn–N3 complexes 1a–1h were synthesized and exhibited high activity and high selectivity under mild conditions. The proposed mechanism was explored through FT-IR, UV-vis, and HRMS, and [ZnLCl 2 I] − Bu 4 N + was demonstrated as the active intermediate.
Authors
- Zhi‐Hong Du (ORCID: https://orcid.org/0000-0002-7408-3588)
- Min Li (ORCID: https://orcid.org/0000-0002-5619-8955)
- Ning Liu (ORCID: https://orcid.org/0000-0001-7299-0400)
- Chunbo Bo
- Mengmeng Li (ORCID: https://orcid.org/0000-0003-1117-8106)
- Fei Chen (ORCID: https://orcid.org/0009-0005-4318-6081)
Institutions
- Shihezi University (CN)
- Green Chemistry (PL)
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj01560j
- Citations
- 1
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.70
Funders
- Government of Xinjiang Uygur Autonomous Region of China
- Shihezi University