Poly(propene-<i>co</i>-norbornene)s with high molar masses and tunable norbornene contents and properties, obtained in high yields using ketimide-modified half-titanocene catalysts
The ketimide half-titanocene catalysts 1–3 yielded high molar mass propene-norbornene copolymers (P- co -N) with efficient N incorporation and tensile properties ranging from ductile and tough materials to stiff and fragile ones as N content increases.
Authors
- Adriano Vignali (ORCID: https://orcid.org/0000-0003-4457-7920)
- Incoronata Tritto (ORCID: https://orcid.org/0000-0001-8364-4298)
- Laura Boggioni (ORCID: https://orcid.org/0000-0001-6476-8447)
- Kotohiro Nomura (ORCID: https://orcid.org/0000-0003-3661-6328)
- Fabio Bertini (ORCID: https://orcid.org/0000-0003-0199-4767)
- Simona Losio (ORCID: https://orcid.org/0000-0003-4333-1523)
- Akira Nishiyama (ORCID: https://orcid.org/0000-0002-5139-8341)
Institutions
- Istituto per le Tecnologie Didattiche (IT)
- Tecnologie Avanzate (Italy) (IT)
- Tokyo Metropolitan University (JP)
Publication Details
- Journal
- Polymer Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5py00549c
- Citations
- 2
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 1.87
Funders
- Japan Society for the Promotion of Science