Chain-section engineering enables electron delocalization for efficient photocatalytic H <sub>2</sub> O <sub>2</sub> synthesis in <scp>d</scp> -glucuronolactone-derived polymers
The all-carbon chain polymer, synthesized <i>via</i> Schiff-base reaction of biomass-derived monomers, enhances electron delocalization/mobility, achieving 3453 μmol g<sup>-1</sup> h<sup>-1</sup> H<sub>2</sub>O<sub>2</sub> yield. It reveals *OOH formation <i>via</i> imine-quinone/hydroxyl synergy, guiding the design of low-cost biomass catalysts for green H<sub>2</sub>O<sub>2</sub> production.
Authors
- Jianning He
- Haijiao Xie
- Shusen Cui (ORCID: https://orcid.org/0000-0003-2840-8166)
- Yu Liu (ORCID: https://orcid.org/0000-0003-1936-0228)
- Qingyao Wu
- Jiawei Lu (ORCID: https://orcid.org/0000-0002-4078-4300)
Institutions
- Hebei Agricultural University (CN)
- Hebei University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03439f
- Primary Topic
- Advanced Photocatalysis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Department of Education of Hebei Province
- Natural Science Foundation of Hebei Province
- Hebei University
- Hebei Agricultural University