Nernst power factor and figure of merit in the compensated semimetal ScSb

Recently, topological semimetals have emerged as strong candidates for solid state thermomagnetic refrigerators due to their enhanced Nernst effect. This enhancement arises from the combined contributions of the Berry curvature induced anomalous Nernst coefficient associated with topological bands and the normal Nernst effect resulting from synergistic electron-hole compensation. Generally, these two effects are intertwined in topological semimetals, making it challenging to evaluate them independently. Here, we report the observation of high Nernst effect in the electron hole compensated semimetal ScSb with topologically trivial electronic band structures. Remarkably, we find a high maximum Nernst power factor of $PF_N \sim 35 \times 10^{-4}$ W m$^{-1}$ K$^{-2}$ in ScSb. The Nernst thermopower ($S_{xy}$) exhibits a peak of $\sim$ 47 $μ$V/K at 12 K and 14 T, yielding a Nernst figure of merit ($z_N$) of $\sim 28 \times 10^{-4}$ K$^{-1}$. Notably, despite its trivial electronic band structure, both the $PF_N$ and $z_N$ values of ScSb are comparable to those observed in topological semimetals with Dirac band dispersions. The origin of the large Nernst signal in ScSb is explained by well compensated electron and hole carriers, through Hall resistivity measurements, angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations.

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Publication Details

Journal
Physical review. B./Physical review. B
Published
2025-07-14
DOI
https://doi.org/10.1103/7vhk-t8t6
Citations
2
Primary Topic
Advanced Thermoelectric Materials and Devices
Type
article
Field-Weighted Citation Impact
1.04

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article

Nernst power factor and figure of merit in the compensated semimetal ScSb

Juntao Yao, Niraj Aryal, Asish K. Kundu, E. Vescovo et al.
2 citations
Physical review. B./Physical review. B
Advanced Thermoelectric Materials and Devices
1.04
article

Nernst power factor and figure of merit in the compensated semimetal ScSb

Juntao Yao, Niraj Aryal, Asish K. Kundu, E. Vescovo, Antu Laha, Sarah Paone, Qiang Li
article en
2 citations

Abstract

Recently, topological semimetals have emerged as strong candidates for solid state thermomagnetic refrigerators due to their enhanced Nernst effect. This enhancement arises from the combined contributions of the Berry curvature induced anomalous Nernst coefficient associated with topological bands and the normal Nernst effect resulting from synergistic electron-hole compensation. Generally, these two effects are intertwined in topological semimetals, making it challenging to evaluate them independently. Here, we report the observation of high Nernst effect in the electron hole compensated semimetal ScSb with topologically trivial electronic band structures. Remarkably, we find a high maximum Nernst power factor of $PF_N \sim 35 \times 10^{-4}$ W m$^{-1}$ K$^{-2}$ in ScSb. The Nernst thermopower ($S_{xy}$) exhibits a peak of $\sim$ 47 $μ$V/K at 12 K and 14 T, yielding a Nernst figure of merit ($z_N$) of $\sim 28 \times 10^{-4}$ K$^{-1}$. Notably, despite its trivial electronic band structure, both the $PF_N$ and $z_N$ values of ScSb are comparable to those observed in topological semimetals with Dirac band dispersions. The origin of the large Nernst signal in ScSb is explained by well compensated electron and hole carriers, through Hall resistivity measurements, angle-resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) calculations.

Physical review. B./Physical review. BVol. 112(4)
Brookhaven National Laboratory (US), Stanford Synchrotron Radiation Lightsource (US), National Synchrotron Light Source II, Stony Brook University (US)
U.S. Department of Energy, Brookhaven National Laboratory
Openalex Percentile: Top 24%
Advanced Thermoelectric Materials and Devices
1.04
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