Dimeric boron complexes bearing isoquinolyl-pyrrole ligands
In the present study, a novel series of dimeric boron complexes bearing 2-(isoquinol-1-yl)pyrrole ligands were synthesized and their optical properties were investigated. The linkage positions of several isoquinoline and pyrrole rings facilitated the control of their molecular orbital energy levels and structural rigidities, thereby determining their characteristic optical properties. Computational studies revealed the detailed relationship between structures and optical properties.
Authors
- Takashi Takeda (ORCID: https://orcid.org/0000-0002-5254-2819)
- Takeo Nakano (ORCID: https://orcid.org/0000-0003-0033-6578)
- Atom Hamasaki (ORCID: https://orcid.org/0000-0002-6112-0992)
- Ryoto Inaba
- Akira Ohta (ORCID: https://orcid.org/0000-0001-6581-4310)
- Haruki Yamada (ORCID: https://orcid.org/0000-0002-8548-0757)
Institutions
- Shinshu University (JP)
- Osaka Research Institute of Industrial Science and Technology (JP)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03519h
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00