Single electron transfer (SET) and iodine-atom transfer radical addition (I-ATRA) induced cyclopropanation reaction: elucidating the role of iodine
Mechanistic studies were conducted for the visible-light-mediated cyclopropanation reaction of alkenes with diazoacetate, catalyzed by a phenalenyl-based organic hydrocarbon (PLY) and co-catalysed by iodine, using DFT.
Authors
- Athul Santha Bhaskaran (ORCID: https://orcid.org/0000-0001-9577-0718)
- Rositha Kuniyil (ORCID: https://orcid.org/0000-0001-5480-3667)
- K. Surya
- Krishnapriya Anattil Unnikrishnan
Institutions
- Indian Institute of Technology Palakkad (IN)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cy00257e
- Citations
- 1
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- Indian Institute of Technology Palakkad
- Department of Science and Technology, Ministry of Science and Technology, India
- Ministry of Education, India
- Science and Engineering Research Board