Dibenzoylmethane in the Synthesis of Selenium Di- and Tetrahydropyridine-3-carbonitriles

3-Cyano-6-hydroxy-1,4,5,6-tetrahydropyridine-2-ammonium selenolates have been synthesized by the reaction of cyanoselenoacetamide, furan-2- or thiophene-2-carbaldehyde, and dibenzoylmethane in ethanol in the presence of an excess of piperidine or morpholine under argon and then used to obtain 2-alkylselenodi- and tetrahydropyridine-3-carbonitriles. The structures of the latter products were analyzed by X-ray diffraction.

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Publication Details

Journal
Russian Journal of Organic Chemistry
Published
2025-05-01
DOI
https://doi.org/10.1134/s1234567825601111
Primary Topic
Organoselenium and organotellurium chemistry
Type
article
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article

Dibenzoylmethane in the Synthesis of Selenium Di- and Tetrahydropyridine-3-carbonitriles

К. А. Фролов, С. Г. Кривоколыско, B. S. Krivokolysko, Nicolai A. Aksenov
Russian Journal of Organic Chemistry
Organoselenium and organotellurium chemistry
article

Dibenzoylmethane in the Synthesis of Selenium Di- and Tetrahydropyridine-3-carbonitriles

К. А. Фролов, С. Г. Кривоколыско, B. S. Krivokolysko, Nicolai A. Aksenov
article en

Abstract

3-Cyano-6-hydroxy-1,4,5,6-tetrahydropyridine-2-ammonium selenolates have been synthesized by the reaction of cyanoselenoacetamide, furan-2- or thiophene-2-carbaldehyde, and dibenzoylmethane in ethanol in the presence of an excess of piperidine or morpholine under argon and then used to obtain 2-alkylselenodi- and tetrahydropyridine-3-carbonitriles. The structures of the latter products were analyzed by X-ray diffraction.

Russian Journal of Organic ChemistryVol. 61(5)
North-Caucasus Federal University (RU), Luhansk State Medical University (UA)
Openalex Percentile: Top 84%
Organoselenium and organotellurium chemistry
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