Sustainable synthesis of 1-thiol-3-alkyl bicyclo[1.1.1]pentanes <i>via</i> electron donor–acceptor complex photoactivation: a metal- and additive-free strategy for bioisostere design

This study demonstrates a green multicomponent reaction driven by electron donor–acceptor (EDA) complex photoactivation, enabling direct alkylation and thiolation of [1.1.1]propellane under metal- and additive-free conditions.

Authors

Binghao Cao (ORCID: https://orcid.org/0009-0009-9810-8071)
Wanmei Li (ORCID: https://orcid.org/0000-0001-6436-7651)
Jingyi Zhang (ORCID: https://orcid.org/0000-0001-6490-4963)
Yibo Wang (ORCID: https://orcid.org/0000-0002-4058-1319)
Yuping Huang (ORCID: https://orcid.org/0000-0001-7942-9704)
Ruiyuan Xu

Institutions

Hangzhou Normal University (CN)

Publication Details

Journal: Green Chemistry
Published: 2025-01-01
DOI: https://doi.org/10.1039/d5gc02067k
Citations: 8
Primary Topic: Sulfur-Based Synthesis Techniques
Type: article
Field-Weighted Citation Impact: 7.49

Funders

Science and Technology Department of Zhejiang Province
Natural Science Foundation of Zhejiang Province

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article

Sustainable synthesis of 1-thiol-3-alkyl bicyclo[1.1.1]pentanes via electron donor–acceptor complex photoactivation: a metal- and additive-free strategy for bioisostere design

Binghao Cao, Wanmei Li, Jingyi Zhang, Yibo Wang et al.

Jan 1, 2025

8 citations

Green Chemistry

Sulfur-Based Synthesis Techniques

7.49

article

Sustainable synthesis of 1-thiol-3-alkyl bicyclo[1.1.1]pentanes via electron donor–acceptor complex photoactivation: a metal- and additive-free strategy for bioisostere design

Binghao Cao, Wanmei Li, Jingyi Zhang, Yibo Wang, Yuping Huang, Ruiyuan Xu

January 1, 2025article en

8 citations

Abstract

This study demonstrates a green multicomponent reaction driven by electron donor–acceptor (EDA) complex photoactivation, enabling direct alkylation and thiolation of [1.1.1]propellane under metal- and additive-free conditions.

Green ChemistryVol. 27(30)

Hangzhou Normal University (CN)

Science and Technology Department of Zhejiang Province, Natural Science Foundation of Zhejiang Province

Openalex Percentile: Top 3%

Sulfur-Based Synthesis Techniques

7.49

DOI Source OpenAlex

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Sustainable synthesis of 1-thiol-3-alkyl bicyclo[1.1.1]pentanes <i>via</i> electron donor–acceptor complex photoactivation: a metal- and additive-free strategy for bioisostere design — Binghao Cao, Wanmei Li, et al. · Green Chemistry (2025) | TGRS Research Map | TGRS