Structure of Sodium and Calcium Metal-Organic Frameworks with 2,2'-Diiodobiphenyl-4,4'-dicarboxylic Acid Anions
The heteroleptic metal-organic frameworks {[Na(μ2-DMF)(HBpdc-I2)]}n (I) and {[Ca(DMF)2(Bpdc-I2)]} (II) were obtained by the reaction of sodium (NaOH) and calcium hydroxides (Ca(OH)2), respectively, with 2,2'-diiodobiphenyl-4,4'-dicarboxylic acid (H2(Bpdc-I2)) in N,N-dimethylformamide (DMF). The product structures were determined by X-ray diffraction. The compounds had two- and three-dimensional structures, respectively. A halogen bond was detected in I between the neighboring Bdc-I2 ligands.
Authors
- А. S. Zaguzin (ORCID: https://orcid.org/0000-0001-7269-1750)
- А. В. Зайцев (ORCID: https://orcid.org/0000-0001-6448-2561)
- Sergey A. Adonin (ORCID: https://orcid.org/0000-0002-9889-5273)
- Н. А. Коробейников
- Mikhail A. Bondarenko
- R. V. Red’kin
- E. A. Pilyukova
Institutions
- Novosibirsk State University (RU)
- A.E. Favorsky Irkutsk Institute of Chemistry (RU)
- Nikolaev Institute of Inorganic Chemistry (RU)
Publication Details
- Journal
- Russian Journal of Coordination Chemistry
- Published
- 2025-04-01
- DOI
- https://doi.org/10.1134/s1070328425600147
- Citations
- 1
- Primary Topic
- Crystallography and molecular interactions
- Type
- article
- Field-Weighted Citation Impact
- 1.75