A Novel Ti <sub>12</sub> ‐Based Metal‐Organic Framework for Photocatalytic Hydrogen Evolution (Adv. Energy Mater. 26/2025)
Photocatalytic Hydrogen Evolution MIP-209(Ti) is a new microporous metal-organic framework (MOF) built up from Ti12O15 clusters and substituted terephthalate linkers, enabling isoreticular chemistry and clusters tunability for photocatalytic applications. Cr3+ doping (≤5 at%) on Ti-oxoclusters enhances water stability and markedly boosts hydrogen production from water under simulated solar light irradiation. Significant photocatalytic activity is achieved without noble metals, paving the way for tunable Ti-MOF-based photocatalysts. More in article number 2500211, Georges Mouchaham, Christian Serre, and co-workers.
Authors
- Arianna Melillo (ORCID: https://orcid.org/0000-0002-6932-9192)
- Beibei Xiao (ORCID: https://orcid.org/0000-0001-9637-7512)
- Sergio Navalón (ORCID: https://orcid.org/0000-0001-8423-0759)
- Philippe Boullay (ORCID: https://orcid.org/0000-0002-2867-8986)
- Bingbing Chen (ORCID: https://orcid.org/0000-0001-5995-4464)
- Celia M. Rueda‐Navarro (ORCID: https://orcid.org/0000-0002-9569-7722)
- Georges Mouchaham (ORCID: https://orcid.org/0000-0001-8696-9733)
- Iurii Dovgaliuk (ORCID: https://orcid.org/0000-0003-1997-4748)
- G. Patriarche (ORCID: https://orcid.org/0000-0002-3917-2470)
- Pierre Florian (ORCID: https://orcid.org/0000-0003-4306-0815)
- Dong Fan
- Christian Serre (ORCID: https://orcid.org/0000-0003-3040-2564)
- Asma Mansouri (ORCID: https://orcid.org/0000-0003-1392-634X)
- Guillaume Maurin (ORCID: https://orcid.org/0000-0002-2096-0450)
- Ieuan Cornu (ORCID: https://orcid.org/0009-0004-5185-920X)
- Lokuge Aravindani Fernando
- Hermenegildo Garcia
- Juan José Ramírez‐Hernández
Institutions
- École Nationale Supérieure de Chimie de Montpellier (FR)
- Université d'Orléans (FR)
- Centre National de la Recherche Scientifique (FR)
- École Nationale Supérieure d'Ingénieurs de Caen (FR)
- Université de Montpellier (FR)
- Université Paris Sciences et Lettres (FR)
- Jiangsu University of Science and Technology (CN)
- Centre de Nanosciences et de Nanotechnologies (FR)
- Conditions Extrêmes et Matériaux Haute Température et Irradiation (FR)
- Universitat Politècnica de València (ES)
- Université de Caen Normandie (FR)
- ESPCI Paris (FR)
Publication Details
- Journal
- Advanced Energy Materials
- Published
- 2025-07-01
- DOI
- https://doi.org/10.1002/aenm.202570112
- Citations
- 2
- Primary Topic
- Advanced Nanomaterials in Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 1.04