Heat Capacities and Thermal Coefficients of Sodium’s and Eutectic Sodium–Potassium’s Coolants for Nuclear Reactors

Temperature dependencies of the density, heat capacity at constant pressure, and isobaric thermal expansion coefficient are investigated for two liquid metal nuclear reactor coolants: pure sodium and sodium–potassium eutectic alloy (31.9 at. %Na). The variational method of the thermodynamic perturbation theory is used for the calculations. The calculations were carried out in temperature ranges of 373–1673 K for Na and 273–1573 K for 0.319Na-0.681K. The accuracy of two local pseudopotentials and three exchange–correlation functions is estimated. It is shown that two combinations between the pseudopotential and exchange–correlation function can be recommended for predicting the properties at high temperatures for which experimental information is absent.