Experimental Study of Electric Conductivity of MPO3(M2WO4)–V2O5 (M = Na, K) Melts

The electric conductivity of binary eutectic oxide–salt composites KPO3–V2O5, NaPO3–V2O5, Na2WO4–V2O5, and K2WO4–V2O5 has been studied. The behavior of the dependence of the conductivity logarithm and specific conductivity on the reciprocal temperature was determined. It was established that the 38 mol % NaPO3–62 mol % V2O5 oxide–salt composite has the highest electric conductivity and is promising for use as an electrolyte for obtaining refractory metals and in chemical current sources.

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Publication Details

Journal
Russian Journal of Physical Chemistry A
Published
2025-07-01
DOI
https://doi.org/10.1134/s0036024425701067
Primary Topic
Catalysis and Oxidation Reactions
Type
article
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article

Experimental Study of Electric Conductivity of MPO3(M2WO4)–V2O5 (M = Na, K) Melts

А. И. Расулов, A. M. Hasanaliev, P. N. Hasanalieva
4 links
Russian Journal of Physical Chemistry A
Catalysis and Oxidation Reactions
article

Experimental Study of Electric Conductivity of MPO3(M2WO4)–V2O5 (M = Na, K) Melts

А. И. Расулов, A. M. Hasanaliev, P. N. Hasanalieva
article en

Abstract

The electric conductivity of binary eutectic oxide–salt composites KPO3–V2O5, NaPO3–V2O5, Na2WO4–V2O5, and K2WO4–V2O5 has been studied. The behavior of the dependence of the conductivity logarithm and specific conductivity on the reciprocal temperature was determined. It was established that the 38 mol % NaPO3–62 mol % V2O5 oxide–salt composite has the highest electric conductivity and is promising for use as an electrolyte for obtaining refractory metals and in chemical current sources.

Russian Journal of Physical Chemistry AVol. 99(7)
Institute of General and Inorganic Chemistry (BG), Dagestan State University (RU), Daghestan State Pedagogical University (RU)
Affordable and clean energy
Openalex Percentile: Top 91%
Catalysis and Oxidation Reactions
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