Improving anti-oxidation properties of metal interconnects in solid oxide fuel cells via a dense Ag-based coating layer

Solid Oxide Fuel Cells (SOFCs) are a highly efficient energy conversion technology, but the degradation of metal interconnects remains a critical challenge. Conventional coatings often lack sufficient electrochemical performance and stability. In this study, a dense Ag coating was developed using the screen-printing method to improve the electrochemical performance and chemical compatibility of SOFC interconnects. Symmetric and single cells were prepared with La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3 − δ cathodes and SUS430 interconnects to evaluate the coating under high-temperature conditions, simulating real SOFC operation. The Ag coating demonstrated excellent adhesion, uniformity, and oxidation resistance, with conductivity increasing from 0.01 to 13.13 S cm −1 at 650 ∘ C after coating and the area-specific resistance decreasing from 1.843 to 0.378 Ω cm 2 after coating between cathode and interconnect at 750 ∘ C. Moreover, the coating effectively inhibited Cr diffusion from the interconnect to the cathode, addressing a major limitation in SOFC durability. These results suggest that Ag coatings offer a practical and promising solution to enhance the performance and extend the lifespan of SOFC systems. • A high conductivity Ag-containing coating was successfully prepared. • The dense protective coating slows the interconnect’s oxidation. • The coating effectively mitigated the increase in area-specific resistance. • Pure metal coatings offer a new approach for interconnects.