On degradation mechanism of lithium-sulfur batteries

Using the method of normalized galvanostatic curves, as well as taking into account the changes in the half-charge and half-discharge potentials of an electrode, the latter based on a sulfur composite with reduced graphene oxide, it was established that the main reason for electrode degradation during cycling was the loss of active material (due to the shuttle transfer of polysulfides and sulfur from the positive electrode to the negative lithium one).

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Publication Details

Journal
Electrochemical Energetics
Published
2025-06-20
DOI
https://doi.org/10.18500/1608-4039-2025-25-2-61-67
Primary Topic
Advanced Battery Materials and Technologies
Type
article
Field-Weighted Citation Impact
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article

On degradation mechanism of lithium-sulfur batteries

Т. Л. Кулова, А. М. Скундин, Sergey A. Li
Electrochemical Energetics
Advanced Battery Materials and Technologies
article

On degradation mechanism of lithium-sulfur batteries

Т. Л. Кулова, А. М. Скундин, Sergey A. Li
article en

Abstract

Using the method of normalized galvanostatic curves, as well as taking into account the changes in the half-charge and half-discharge potentials of an electrode, the latter based on a sulfur composite with reduced graphene oxide, it was established that the main reason for electrode degradation during cycling was the loss of active material (due to the shuttle transfer of polysulfides and sulfur from the positive electrode to the negative lithium one).

Electrochemical EnergeticsVol. 25(2)
Openalex Percentile: Top 86%
Advanced Battery Materials and Technologies
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On degradation mechanism of lithium-sulfur batteries — Т. Л. Кулова, А. М. Скундин, et al. · Electrochemical Energetics (2025) | TGRS Research Map | TGRS