Analyzing Thermal Characteristics of a Salt-based Phase Change Material with the Addition of Nanoparticles

The effective storage of thermal energy is essential for the progress of green energy systems.Sodium acetate trihydrate (SATH), a potential inorganic phase change material (PCM), is frequently constrained by its inadequate thermal conductivity and significant supercooling tendency.This work integrated nano-ZnO particles into SATH at different mass fractions (0-2.0%) to create nano-enhanced phase change materials (nano-PCMs) with increased thermal properties.The nano-ZnO/SATH phase change materials (PCMs) were analysed by differential scanning calorimetry (DSC), field emission scanning electron microscopy (FESEM), and thermal conductivity testing.The findings indicated that incorporating 1.0% mass of nano-ZnO significantly decreased supercooling from 35C to 1.48C and attained the maximum latent heat value (239.7 kJ/kg) across all tested nano-PCMs.Thermal conductivity demonstrated a steady increase with nanoparticle concentration, achieving a maximum boost of 27.96% at a 2.0% mass fraction.Increased nanoparticle dosage above 1.0%resulted in reduced latent heat capacity due to clustering phenomena.This study illustrates that optimised nano-ZnO incorporation may significantly boost the efficacy of salt-based phase change materials, with prospective applications in thermal energy storage systems necessitating improved heat transmission and thermal dependability.

Publication Details

Journal
Malaysian Journal of Chemistry
Published
2025-06-20
DOI
https://doi.org/10.55373/mjchem.v27i3.490
Primary Topic
Material Properties and Applications
Type
article
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article

Analyzing Thermal Characteristics of a Salt-based Phase Change Material with the Addition of Nanoparticles

Malaysian Journal of Chemistry
Material Properties and Applications
article

Analyzing Thermal Characteristics of a Salt-based Phase Change Material with the Addition of Nanoparticles

article en

Abstract

The effective storage of thermal energy is essential for the progress of green energy systems.Sodium acetate trihydrate (SATH), a potential inorganic phase change material (PCM), is frequently constrained by its inadequate thermal conductivity and significant supercooling tendency.This work integrated nano-ZnO particles into SATH at different mass fractions (0-2.0%) to create nano-enhanced phase change materials (nano-PCMs) with increased thermal properties.The nano-ZnO/SATH phase change materials (PCMs) were analysed by differential scanning calorimetry (DSC), field emission scanning electron microscopy (FESEM), and thermal conductivity testing.The findings indicated that incorporating 1.0% mass of nano-ZnO significantly decreased supercooling from 35C to 1.48C and attained the maximum latent heat value (239.7 kJ/kg) across all tested nano-PCMs.Thermal conductivity demonstrated a steady increase with nanoparticle concentration, achieving a maximum boost of 27.96% at a 2.0% mass fraction.Increased nanoparticle dosage above 1.0%resulted in reduced latent heat capacity due to clustering phenomena.This study illustrates that optimised nano-ZnO incorporation may significantly boost the efficacy of salt-based phase change materials, with prospective applications in thermal energy storage systems necessitating improved heat transmission and thermal dependability.

Malaysian Journal of ChemistryVol. 27(3)
Openalex Percentile: Top 74%
Material Properties and Applications
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