Geochemical Characteristics and Paleoenvironmental Significance of the Xishanyao Formation Coal from the Xiheishan Mining Area, Zhundong Coalfield, Xinjiang, China

The eastern Junggar Basin in Xinjiang, China is a key coal-bearing region dominated by the Middle Jurassic Xishanyao Formation. Despite its significance as a major coal resource base, detailed paleoenvironmental reconstructions of its coal seams remain limited. This study investigates the B1, B2, B3, and B5 coal seams of the Xishanyao Formation using X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma mass spectrometry (ICP-MS) to assess geochemical indicators of the depositional environment during coal formation. The results show that the coal samples are characterized by high inertinite content and low vitrinite reflectance, indicative of low-rank coal. Slight enrichment of strontium (Sr) was observed in the B1, B2, and B5 seams, while cobalt (Co) showed minor enrichment in B3. Redox-sensitive elemental ratios (Ni/Co, V/Cr, and Mo) suggest that the peat-forming environment ranged from oxidizing to dysoxic conditions, with relatively high oxygen availability and strong hydrodynamic activity. A vertical trend of increasing paleosalinity and a shift from warm–humid to dry–hot paleoclimatic conditions was identified from the lower (B1) to upper (B5) coal seams. Additionally, the estimated atmospheric oxygen concentration during the Middle Jurassic was approximately 28.4%, well above the threshold for wildfire combustion. These findings provide new insights into the paleoenvironmental evolution of the Xishanyao Formation and offer a valuable geochemical framework for coal exploration and the assessment of coal-associated mineral resources in the eastern Junggar Basin.