Photocatalytic cleavage of unactivated C(sp<sup>3</sup>)–H bonds <i>via</i> the uranyl cation: enabling the allylation of alkanes

The uranyl cation serves as a highly efficient direct hydrogen atom transfer ( d -HAT) catalyst, enabling direct allylation of C(sp 3 )–H bonds with broad substrate compatibility, scalability, and potential for diverse functionalization.

Authors

Y Z Luo (ORCID: https://orcid.org/0009-0009-6783-8733)
Yanxin Jiang
S. H. Tang (ORCID: https://orcid.org/0009-0000-7001-9493)
Jing Su (ORCID: https://orcid.org/0000-0002-6895-2150)
Zixin Wang (ORCID: https://orcid.org/0000-0002-3604-860X)
Zekai Li (ORCID: https://orcid.org/0009-0002-0143-4057)

Institutions

Sichuan University (CN)

Publication Details

Journal: Organic Chemistry Frontiers
Published: 2025-01-01
DOI: https://doi.org/10.1039/d5qo00649j
Citations: 2
Primary Topic: Catalytic C–H Functionalization Methods
Type: article
Field-Weighted Citation Impact: 1.87

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article

Photocatalytic cleavage of unactivated C(sp³)–H bonds via the uranyl cation: enabling the allylation of alkanes

Y Z Luo, Yanxin Jiang, S. H. Tang, Jing Su et al.

Jan 1, 2025

2 citations

Organic Chemistry Frontiers

Catalytic C–H Functionalization Methods

1.87

article

Photocatalytic cleavage of unactivated C(sp³)–H bonds via the uranyl cation: enabling the allylation of alkanes

Y Z Luo, Yanxin Jiang, S. H. Tang, Jing Su, Zixin Wang, Zekai Li

January 1, 2025article en

2 citations

Abstract

The uranyl cation serves as a highly efficient direct hydrogen atom transfer ( d -HAT) catalyst, enabling direct allylation of C(sp 3 )–H bonds with broad substrate compatibility, scalability, and potential for diverse functionalization.

Organic Chemistry FrontiersVol. 12(21)

Sichuan University (CN)

Openalex Percentile: Top 15%

Catalytic C–H Functionalization Methods

1.87

DOI Source OpenAlex

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