Stereoisomers of metal–organic dimers induced by the steric constraint of dissymmetric terpyridine ligands
Herein, we report a novel molecular design strategy for constructing stereoisomers based on dissymmetric modified ligands and closely packed dimeric structures. X-ray analyses reveal that different substituents have an important effect on stereoisomers and can provide various driving forces to realize the adjustment of crystal packing.
Authors
- Houyu Zhang (ORCID: https://orcid.org/0000-0003-0360-6035)
- Jianjun Ma (ORCID: https://orcid.org/0000-0002-2563-6369)
- Hao Yu (ORCID: https://orcid.org/0000-0002-1594-769X)
- Junmin Chang (ORCID: https://orcid.org/0000-0003-3289-0602)
- Kehuan Li (ORCID: https://orcid.org/0000-0001-6403-2616)
- Junjuan Shi (ORCID: https://orcid.org/0000-0003-2564-5975)
- Jiaqi Li (ORCID: https://orcid.org/0000-0003-2199-9565)
- Ning Zhang (ORCID: https://orcid.org/0000-0002-6176-7278)
- Ming Wang (ORCID: https://orcid.org/0000-0002-5332-0804)
- Ningxu Han (ORCID: https://orcid.org/0000-0001-5135-1175)
Institutions
- Xinjiang Medical University (CN)
- Jilin University (CN)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt00948k
- Citations
- 1
- Primary Topic
- Supramolecular Chemistry and Complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- Natural Science Foundation of Jilin Province
- Natural Science Foundation of Xinjiang Province
- National Natural Science Foundation of China
- China Postdoctoral Science Foundation