Copper-catalyzed stereo-controllable silylation of allylic <i>gem</i>-dichlorides
A copper-catalyzed stereodivergent silylation of allylic gem-dichlorides was developed: ligand-free conditions gave ( Z )-vinyl chlorides, while chiral Pybox ligands enabled access to enantiopure ( E )-vinyl chlorides in high yield.
Authors
- Yun‐He Xu (ORCID: https://orcid.org/0000-0001-8817-0626)
- Zi‐Lu Wang (ORCID: https://orcid.org/0000-0002-1187-7508)
- Panpan Tian
Institutions
- University of Science and Technology of China (CN)
- Nanjing University of Posts and Telecommunications (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00690b
- Primary Topic
- Coordination Chemistry and Organometallics
- Type
- article
- Field-Weighted Citation Impact
- 0.00