Effects of MFI Zeolite Acidity on Protein Adsorption

Isotherms were recorded for the adsorption of chicken egg lysozyme and bovine serum albumin (BSA) on MFI zeolites with different concentrations of acid sites (from 15 to 1000 μmol/g). The maximum adsorption capacities were evaluated, and the correlation between acid site concentration and protein adsorption capacity was identified. The sample with the highest acidity exhibited the highest adsorption capacity. The protein adsorption reduced the total acid site concentration by 20–30% and simultaneously increased the relative content of weak sites. Furthermore, the adsorption affected the IR spectra of the proteins.

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Journal
Petroleum Chemistry
Published
2025-04-01
DOI
https://doi.org/10.1134/s0965544125600845
Primary Topic
Adsorption and biosorption for pollutant removal
Type
article
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article

Effects of MFI Zeolite Acidity on Protein Adsorption

L. F. Atyaksheva, V. A. Vorobkalo, D. O. Bachurina, Egor P. Andriako et al.
Petroleum Chemistry
Adsorption and biosorption for pollutant removal
article

Effects of MFI Zeolite Acidity on Protein Adsorption

L. F. Atyaksheva, V. A. Vorobkalo, D. O. Bachurina, Egor P. Andriako, Борис Н. Тарасевич, A. V. Smagin, A. V. Efimov
article en

Abstract

Isotherms were recorded for the adsorption of chicken egg lysozyme and bovine serum albumin (BSA) on MFI zeolites with different concentrations of acid sites (from 15 to 1000 μmol/g). The maximum adsorption capacities were evaluated, and the correlation between acid site concentration and protein adsorption capacity was identified. The sample with the highest acidity exhibited the highest adsorption capacity. The protein adsorption reduced the total acid site concentration by 20–30% and simultaneously increased the relative content of weak sites. Furthermore, the adsorption affected the IR spectra of the proteins.

Petroleum ChemistryVol. 65(4)
Russian Academy of Sciences (RU), Lomonosov Moscow State University (RU), A.V. Topchiev Institute of Petrochemical Synthesis (RU)
Openalex Percentile: Top 85%
Adsorption and biosorption for pollutant removal
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