Mo–V/g-C<sub>3</sub>N<sub>4</sub> with strong electron donating capacity and abundant oxygen vacancies for low-temperature aerobic oxidative desulfurization
Mo-V/g-C<sub>3</sub>N<sub>4</sub> with varying oxygen vacancy contents were prepared <i>via</i> successive H<sub>2</sub> and NaBH<sub>4</sub> reduction. The oxygen vacancies could enhance oxygen adsorption while π-conjugated g-C<sub>3</sub>N<sub>4</sub> support could promote surface electron transfer capacity, both facilitating the activation of oxygen into reactive oxygen species superoxide radicals. The catalyst achieves 100% aerobic oxidative desulfurization performance at 80 °C.
Authors
- Xuelin Tian (ORCID: https://orcid.org/0000-0001-6178-2067)
- Jia Guo (ORCID: https://orcid.org/0000-0002-6422-2302)
- Hong Liu (ORCID: https://orcid.org/0000-0001-7930-7088)
- Jiasheng Wang (ORCID: https://orcid.org/0000-0001-6519-4318)
Institutions
- Dalian University of Technology (CN)
- Dalian University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02128f
- Citations
- 3
- Primary Topic
- Catalysis and Hydrodesulfurization Studies
- Type
- article
- Field-Weighted Citation Impact
- 2.14
Funders
- National Natural Science Foundation of China