Chemical recycling of polylactide by microwave-assisted processes

The chemical recycling of post-consumer polylactic acid by microwave-assisted alcoholysis promoted by a phenoxy-imine pyridine zinc is investigated. Different alcohols and diols are used to achieve, in all cases, outstanding activity and selectivity toward the targeted products. Thanks to the robustness of the catalyst the reactions can be performed in the air, with technical grade reagents and without the use of additional solvents, thus ensuring the full sustainability of the procedure.

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Publication Details

Journal
Faraday Discussions
Published
2025-06-30
DOI
https://doi.org/10.1039/d5fd00078e
Primary Topic
Recycling and Waste Management Techniques
Type
article
Field-Weighted Citation Impact
0.00

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article

Chemical recycling of polylactide by microwave-assisted processes

Mina Mazzeo, Maria Rosaria Acocella, Marina Lamberti, Federica Santulli et al.
Faraday Discussions
Recycling and Waste Management Techniques
article

Chemical recycling of polylactide by microwave-assisted processes

Mina Mazzeo, Maria Rosaria Acocella, Marina Lamberti, Federica Santulli, Mauro Pio Ferrandino, Costantino Cioffi
article en

Abstract

The chemical recycling of post-consumer polylactic acid by microwave-assisted alcoholysis promoted by a phenoxy-imine pyridine zinc is investigated. Different alcohols and diols are used to achieve, in all cases, outstanding activity and selectivity toward the targeted products. Thanks to the robustness of the catalyst the reactions can be performed in the air, with technical grade reagents and without the use of additional solvents, thus ensuring the full sustainability of the procedure.

Faraday DiscussionsVol. 262(0)
University of Salerno (IT), Consorzio Interuniversitario Reattività Chimica e Catalisi (IT)
European Commission
Openalex Percentile: Top 81%
Recycling and Waste Management Techniques
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