Research Progress on the Stability and Durability of Ag/AgCl Prepared by Anodic Chlorination Method for Chloride Ion Sensors in Cement-Based Materials

A strong application potential for Ag/AgCl ion-selective electrodes (ISEs) used as chloride sensors in cement-based material is widely accepted, but their stability and durability have not been sufficiently addressed. This paper summarizes the research status of the stability and durability of Ag/AgCl ISEs used for the non-destructive detection of chloride in cement-based materials. Four topics including working principle and fabrication methods, the factors that influence stability, research status for stability and durability studies, and the reason for durability failure of Ag/AgCl ISEs in cement-based materials are reviewed. Meanwhile, the improving methods for Ag/AgCl ISEs are proposed based on discussions of various aspects of Ag/AgCl ISEs.