Hydrodynamic Cavitation-Assisted Hydrothermal Separation: A Pathway for Valorizing Lignocellulosic Biomass into Biopolymers and Extractives

Lignocellulosic biomass is a sustainable renewable resource for producing biopolymers, chemicals, and high-value compounds. This study proposes a biomass valorization concept that combines hydrodynamic cavitation (HC) and hydrothermal separation (HTS) to produce high-value products. Aspen Plus software was used in this study to develop the first simulation-driven integration of HC and HTS for biomass valorization in the biorefinery concept. The overall separation efficiency and component yield for standalone HC and HTS processes agreed with the experimental data. The findings from the simulation results indicate that the coupled processes yielded a significant enhancement in overall separation efficiency. This coupling resulted in a 24.5% increase compared to a single HC process and 16.75% higher efficiency than a single HTS process for sugarcane bagasse. The sensitivity analysis showed that incrementing HTS temperature and reaction time results in higher component yield and overall separation efficiency. The increase in the S/L ratio demonstrated a higher component yield in the process downstream, whereas the efficiency remained approximately the same. The effect of the HTS pressure was negligible on component yield and overall separation efficiency. Moreover, this study identified the optimal process parameters of the coupled process. At the optimal condition, quadratic models showed an overall separation efficiency of 79.41 ± 2.71% for the HC-HTS coupled process. This approach promises superior biomass utilization over traditional processes, minimizing waste and environmental impact while expanding the potential applications of biomass.