Mechanochemical Synthesis and Electron Crystallography Characterization of van der Waals Lanthanoid 2D Metal–Organic Frameworks
Mechanochemical synthesis provides access to clean, effective, and rapid synthesis of 2D van der Waals MOFs [Ln(MeCOO)(PhCOO)<sub>2</sub>] (<b>1Eu</b>, <b>2Eu</b>, <b>2Tb</b>). The method also allows easy access to heterometallic analogue <b>2LaTb</b>. All samples are obtained as nanosized crystals, and <b>1Eu</b> has been characterized by electron crystallography (3D-ED). Thus, mechanochemistry and 3D-ED is a winning combination for the clean synthesis of 2D MOFs that can be upscaled to multigram synthesis.
Authors
- Helena Fernández Cortés
- Sara P. Dias (ORCID: https://orcid.org/0000-0002-0115-4840)
- Eva Carolina Sañudo (ORCID: https://orcid.org/0000-0001-9647-6406)
- Javier Collado (ORCID: https://orcid.org/0000-0002-8707-6619)
- César Santiago (ORCID: https://orcid.org/0000-0002-5149-1722)
- Rocío Arranz (ORCID: https://orcid.org/0000-0001-5321-0915)
- Lorenzo Franco (ORCID: https://orcid.org/0009-0005-6231-6056)
- Francisco Javier Chichón (ORCID: https://orcid.org/0000-0003-2766-0327)
- Chrysanthi Katsavou
- Kevin Parada Rolán
Institutions
- Institut de Nanociència i Nanotecnologia de la Universitat de Barcelona
- Universidad Autónoma de Madrid (ES)
- Universitat de Barcelona (ES)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2025-06-27
- DOI
- https://doi.org/10.1021/acs.inorgchem.5c01592
- Citations
- 3
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.61
Funders
- Ministerio de Ciencia, Innovación y Universidades
- European Regional Development Fund