Melt-quenched synthesis of a manganese ZIF glass
In this work we expand the family of ZIFs capable of being melt-quenched into a vitreous phase with the first Mn-based glass. This is achieved by preparing two new Mn-based ZIFs with topologies <b>dia-c</b> and <b>zni</b><i>via</i> solvent-free synthesis and subsequent melting. This study also provides a direct comparison of metal effects on melting and decomposition behaviour, highlighting the relationship between bond strength and thermal properties.
Authors
- Luis León‐Alcaide (ORCID: https://orcid.org/0000-0003-1667-0618)
- Guillermo Mı́nguez Espallargas (ORCID: https://orcid.org/0000-0001-7855-1003)
- Alberto Fernández‐Alarcón (ORCID: https://orcid.org/0000-0002-3282-9759)
- David A. Keen (ORCID: https://orcid.org/0000-0003-0376-2767)
- Joaquín Calbo (ORCID: https://orcid.org/0000-0003-4729-0757)
Institutions
- Rutherford Appleton Laboratory (GB)
- Parc Científic de la Universitat de València (ES)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc02342d
- Primary Topic
- Cultural Heritage Materials Analysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- European Commission
- Generalitat Valenciana
- Universitat de València
- Agencia Estatal de Investigación