Solubilizing dimolybdenum paddlewheel complexes for energy storage applications

Three paddlewheel-type Mo≣Mo complexes incorporating the solubilizing carboxylate ligands 2-(2-methoxyethoxy)acetate, isovalerate, and 5-methylhexanoate were prepared and characterised for potential use in energy storage applications. Along with a previously reported compound, the series demonstrates control over properties including solubility, reduction potential, and Li<sup>+</sup> binding in electrolytes relevant to Li batteries.

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Publication Details

Journal
Dalton Transactions
Published
2025-01-01
DOI
https://doi.org/10.1039/d5dt01246e
Primary Topic
Polyoxometalates: Synthesis and Applications
Type
article
Field-Weighted Citation Impact
0.00

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article

Solubilizing dimolybdenum paddlewheel complexes for energy storage applications

Neal P. Mankad, Simon G. Gersib, S. M. Supundrika Subasinghe
Dalton Transactions
Polyoxometalates: Synthesis and Applications
article

Solubilizing dimolybdenum paddlewheel complexes for energy storage applications

Neal P. Mankad, Simon G. Gersib, S. M. Supundrika Subasinghe
article en

Abstract

Three paddlewheel-type Mo≣Mo complexes incorporating the solubilizing carboxylate ligands 2-(2-methoxyethoxy)acetate, isovalerate, and 5-methylhexanoate were prepared and characterised for potential use in energy storage applications. Along with a previously reported compound, the series demonstrates control over properties including solubility, reduction potential, and Li<sup>+</sup> binding in electrolytes relevant to Li batteries.

Dalton TransactionsVol. 54(27)
University of Illinois Chicago (US), University of Chicago (US)
National Science Foundation, Division of Chemistry
Affordable and clean energy
Openalex Percentile: Top 90%
Polyoxometalates: Synthesis and Applications
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