Transition-metal-free K<sub>2</sub>S<sub>2</sub>O<sub>8</sub>-promoted oxidative C–C triple bond cleavage and esterification leading to α-ketoesters
A sustainable method for converting alkynes into α-ketoesters is reported through K<sub>2</sub>S<sub>2</sub>O<sub>8</sub>-promoted oxidative C-C triple bond cleavage and esterification. This approach avoids transition metal catalysis, photocatalysts, and pure oxygen conditions, making it both efficient and more convenient.
Authors
- Wenchao Yang (ORCID: https://orcid.org/0000-0001-7729-7365)
- Fei Meng (ORCID: https://orcid.org/0000-0003-3084-2607)
- Yang Zhou (ORCID: https://orcid.org/0000-0003-0377-4338)
- Liu‐Yu Shen
- Yu Shu
- J. Y. Lan
Institutions
- Yangzhou University (CN)
Publication Details
- Journal
- Organic & Biomolecular Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ob00892a
- Citations
- 4
- Primary Topic
- Chemical Synthesis and Reactions
- Type
- article
- Field-Weighted Citation Impact
- 3.74