Scalable Synthesis of CsPbX<sub>3</sub> Quantum Dot–Organic Hybrid Microrings for Low Threshold Lasing
Perovskite colloidal quantum dots (PQDs) are nanoscale crystals renowned for their exceptional optical properties, making them ideal for next-generation laser technologies. Their solution-processability supports thin-film fabrication and microcavity integration, yet micro-nano laser development remains challenging. In this study, we present a template-confined growth approach to fabricate hybrid microring (HMR) arrays, embedding PQDs within a 4,4'-bis(9-carbazolyl)-1,1'-biphenyl (CBP) matrix. This method produces uniform structures with improved processability. Structural characterization reveals a vertically graded PQD distribution, with higher concentrations near the substrate due to accumulation during CBP's bottom-up precipitation. CBP integration enhances processability and lowers PQD density, suppressing Auger recombination. These HMRs, featuring smooth surfaces, serve as efficient whispering gallery mode (WGM) resonators, achieving laser emission at a threshold of 6.64 μJ cm<sup>-2</sup> and a quality factor of 1808. Tunable ring dimensions enable precise mode control, while scalability supports large-area production of blue, green, and red HMRs, advancing integrated photonics.
Authors
- Yi Ding (ORCID: https://orcid.org/0000-0002-1347-2811)
- Haihua Zhang (ORCID: https://orcid.org/0000-0001-8279-7903)
- Hongbing Fu (ORCID: https://orcid.org/0000-0003-4528-189X)
Institutions
- Tianjin University (CN)
- Collaborative Innovation Center of Chemical Science and Engineering Tianjin (CN)
- Capital Normal University (CN)
Publication Details
- Journal
- The Journal of Physical Chemistry Letters
- Published
- 2025-06-24
- DOI
- https://doi.org/10.1021/acs.jpclett.5c01111
- Citations
- 2
- Primary Topic
- Perovskite Materials and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.46
Funders
- National Natural Science Foundation of China
- Natural Science Foundation of Tianjin City
- National Science and Technology Major Project
- Fundamental Research Funds for the Central Universities