Scalable Synthesis of CsPbX<sub>3</sub> Quantum Dot–Organic Hybrid Microrings for Low Threshold Lasing

Perovskite colloidal quantum dots (PQDs) are nanoscale crystals renowned for their exceptional optical properties, making them ideal for next-generation laser technologies. Their solution-processability supports thin-film fabrication and microcavity integration, yet micro-nano laser development remains challenging. In this study, we present a template-confined growth approach to fabricate hybrid microring (HMR) arrays, embedding PQDs within a 4,4'-bis(9-carbazolyl)-1,1'-biphenyl (CBP) matrix. This method produces uniform structures with improved processability. Structural characterization reveals a vertically graded PQD distribution, with higher concentrations near the substrate due to accumulation during CBP's bottom-up precipitation. CBP integration enhances processability and lowers PQD density, suppressing Auger recombination. These HMRs, featuring smooth surfaces, serve as efficient whispering gallery mode (WGM) resonators, achieving laser emission at a threshold of 6.64 μJ cm<sup>-2</sup> and a quality factor of 1808. Tunable ring dimensions enable precise mode control, while scalability supports large-area production of blue, green, and red HMRs, advancing integrated photonics.

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Publication Details

Journal
The Journal of Physical Chemistry Letters
Published
2025-06-24
DOI
https://doi.org/10.1021/acs.jpclett.5c01111
Citations
2
Primary Topic
Perovskite Materials and Applications
Type
article
Field-Weighted Citation Impact
1.46

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article

Scalable Synthesis of CsPbX3 Quantum Dot–Organic Hybrid Microrings for Low Threshold Lasing

Yi Ding, Haihua Zhang, Hongbing Fu
2 citations
The Journal of Physical Chemistry Letters
Perovskite Materials and Applications
1.46
article

Scalable Synthesis of CsPbX3 Quantum Dot–Organic Hybrid Microrings for Low Threshold Lasing

Yi Ding, Haihua Zhang, Hongbing Fu
article en
2 citations

Abstract

Perovskite colloidal quantum dots (PQDs) are nanoscale crystals renowned for their exceptional optical properties, making them ideal for next-generation laser technologies. Their solution-processability supports thin-film fabrication and microcavity integration, yet micro-nano laser development remains challenging. In this study, we present a template-confined growth approach to fabricate hybrid microring (HMR) arrays, embedding PQDs within a 4,4'-bis(9-carbazolyl)-1,1'-biphenyl (CBP) matrix. This method produces uniform structures with improved processability. Structural characterization reveals a vertically graded PQD distribution, with higher concentrations near the substrate due to accumulation during CBP's bottom-up precipitation. CBP integration enhances processability and lowers PQD density, suppressing Auger recombination. These HMRs, featuring smooth surfaces, serve as efficient whispering gallery mode (WGM) resonators, achieving laser emission at a threshold of 6.64 μJ cm<sup>-2</sup> and a quality factor of 1808. Tunable ring dimensions enable precise mode control, while scalability supports large-area production of blue, green, and red HMRs, advancing integrated photonics.

The Journal of Physical Chemistry LettersVol. 16(26)
Tianjin University (CN), Collaborative Innovation Center of Chemical Science and Engineering Tianjin (CN), Capital Normal University (CN)
National Natural Science Foundation of China, Natural Science Foundation of Tianjin City, National Science and Technology Major Project, Fundamental Research Funds for the Central Universities
Zero hunger
Openalex Percentile: Top 17%
Perovskite Materials and Applications
1.46
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Scalable Synthesis of CsPbX<sub>3</sub> Quantum Dot–Organic Hybrid Microrings for Low Threshold Lasing — Yi Ding, Haihua Zhang, et al. · The Journal of Physical Chemistry Letters (2025) | TGRS Research Map | TGRS