Solvent Performance Evaluation of Heavy Oil in Coal–Oil Co-Liquefaction

In this study, we investigated the solvent performance of six heavy oils from Xinjiang, China, for coal-oil co-liquefaction (COCL). Autoclave experiments revealed that shale oil vacuum residue (SOVR) provided the best liquefaction performance. The oils were characterized using FT-IR, <sup>13</sup>C-NMR, <sup>1</sup>H-NMR, and column chromatography, which revealed that they were mainly composed of aliphatic compounds, with minor aromatic and substituted aromatic compounds. The pyrolytic degradation quality indices (PDQIs), solubility parameter (δ<sub>C</sub>), and polycyclic aromatic hydrocarbon content (H<sub>A2</sub> + H<sub>A3</sub>) were calculated and correlated with liquefaction performance. The results showed a strong linear relationship between H<sub>A2</sub> + H<sub>A3</sub> and oil yield (R<sup>2</sup> = 0.90), and the aromatic content (AR) was also positively related to oil yield. This study suggests that AR content and H<sub>A2</sub> + H<sub>A3</sub> are effective indicators for evaluating the solvent performance of heavy oils in COCL.

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Publication Details

Journal
International Journal of Molecular Sciences
Published
2025-06-24
DOI
https://doi.org/10.3390/ijms26136048
Citations
1
Primary Topic
Petroleum Processing and Analysis
Type
article
Field-Weighted Citation Impact
0.75

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article

Solvent Performance Evaluation of Heavy Oil in Coal–Oil Co-Liquefaction

Yingluo He, C. Y. Chen, Ting Liu, Tingting Cui et al.
1 citations
International Journal of Molecular Sciences
Petroleum Processing and Analysis
0.75
article

Solvent Performance Evaluation of Heavy Oil in Coal–Oil Co-Liquefaction

Yingluo He, C. Y. Chen, Ting Liu, Tingting Cui, Guanghua Yang, Juan Ma
article en
1 citations

Abstract

In this study, we investigated the solvent performance of six heavy oils from Xinjiang, China, for coal-oil co-liquefaction (COCL). Autoclave experiments revealed that shale oil vacuum residue (SOVR) provided the best liquefaction performance. The oils were characterized using FT-IR, <sup>13</sup>C-NMR, <sup>1</sup>H-NMR, and column chromatography, which revealed that they were mainly composed of aliphatic compounds, with minor aromatic and substituted aromatic compounds. The pyrolytic degradation quality indices (PDQIs), solubility parameter (δ<sub>C</sub>), and polycyclic aromatic hydrocarbon content (H<sub>A2</sub> + H<sub>A3</sub>) were calculated and correlated with liquefaction performance. The results showed a strong linear relationship between H<sub>A2</sub> + H<sub>A3</sub> and oil yield (R<sup>2</sup> = 0.90), and the aromatic content (AR) was also positively related to oil yield. This study suggests that AR content and H<sub>A2</sub> + H<sub>A3</sub> are effective indicators for evaluating the solvent performance of heavy oils in COCL.

International Journal of Molecular SciencesVol. 26(13)
University of Toyama (JP), Xinjiang University (CN)
Natural Science Foundation of Xinjiang Province, Natural Science Foundation of Xinjiang, National Key Research and Development Program of China
Openalex Percentile: Top 30%
Petroleum Processing and Analysis
0.75
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Solvent Performance Evaluation of Heavy Oil in Coal–Oil Co-Liquefaction — Yingluo He, C. Y. Chen, et al. · International Journal of Molecular Sciences (2025) | TGRS Research Map | TGRS