Hydro- and chloroelementation reactions across an iron–carbon bond using heavy group 15 reagents
Diaminostibines ({Sb}-H) add across the iron-carbon bond of a tucked-in iron diphosphine complex, resulting in hydrostibinated iron hydride [{Cp*-SbR<sub>2</sub>}Fe-H] complexes. The scope was broadened to include {Sb}-Cl and {Bi}-Cl chloroelementation reactions, providing new and mild synthetic pathways to Sb- and Bi-containing heteroorganometallics.
Authors
- Marcus W. Drover (ORCID: https://orcid.org/0000-0002-2186-1040)
- Joseph A. Zurakowski (ORCID: https://orcid.org/0000-0001-6903-5787)
- Saurabh S. Chitnis (ORCID: https://orcid.org/0000-0001-9180-7907)
- Connor S. Durfy (ORCID: https://orcid.org/0000-0003-0213-6625)
- Paul D. Boyle (ORCID: https://orcid.org/0000-0001-6161-6333)
- Mitchell A. Z. MacEachern
Institutions
- Western University (CA)
- Dalhousie University (CA)
- University of Windsor (CA)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc03258j
- Citations
- 1
- Primary Topic
- Asymmetric Hydrogenation and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.54
Funders
- Canada Foundation for Innovation
- Natural Sciences and Engineering Research Council of Canada