Pd-Catalyzed [2+2+2] Coupling-Cyclization of Sila-Enynes with Arylsulfonyl Chlorides

A novel Pd(0)-catalyzed [2+2+2] coupling-cyclization of sila-enynes with sulfonylarenes has been developed. The method provides a concise approach to access nonaromatizable benzosilacycle skeleton molecules.

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Publication Details

Journal
The Journal of Organic Chemistry
Published
2025-06-24
DOI
https://doi.org/10.1021/acs.joc.5c00524
Primary Topic
Catalytic Alkyne Reactions
Type
article
Field-Weighted Citation Impact
0.00

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article

Pd-Catalyzed [2+2+2] Coupling-Cyclization of Sila-Enynes with Arylsulfonyl Chlorides

Wei Zeng, Huanfeng Jiang, Yukun Li, Luo Liu et al.
The Journal of Organic Chemistry
Catalytic Alkyne Reactions
article

Pd-Catalyzed [2+2+2] Coupling-Cyclization of Sila-Enynes with Arylsulfonyl Chlorides

Wei Zeng, Huanfeng Jiang, Yukun Li, Luo Liu, F.‐C. HUANG
article en

Abstract

A novel Pd(0)-catalyzed [2+2+2] coupling-cyclization of sila-enynes with sulfonylarenes has been developed. The method provides a concise approach to access nonaromatizable benzosilacycle skeleton molecules.

The Journal of Organic ChemistryVol. 90(26)
Key Laboratory of Guangdong Province (CN), South China University of Technology (CN)
National Natural Science Foundation of China, Basic and Applied Basic Research Foundation of Guangdong Province
Openalex Percentile: Top 89%
Catalytic Alkyne Reactions
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